دراسة تعقيد Ce(III) و Ce(IV) مع بعض مشتقات رباعي أريل µ-إيميدو ثنائي الفوسفات
Abstract
تم تحضير المركبات الفوسفورية العضوية التالية: ثنائي فينيل ثنائي بارا نترو فينيل إستر إيميدو ثنائي الفوسفات (p-nitroPhO)2P(O)N(H)P(O)(OPh)2, ثنائي بارا نترو فينيل إستر إيميدو ثنائي الفوسفات
(p-nitroPhO)2P(O)N(H)P(O)(OH)2 , إذ استخدمت لتحضير معقداتها مع Ce(III) و Ce(IV) في وسط كحولي (إيتانول) وذلك من خلال مزج المحاليل الكحولية لنترات السيريوم(III) وكبريتات السيريوم (IV) كلاً على حدا مع المحاليل الكحولية للمركبات المذكورة سابقاً في درجة حرارة منخفضة (-15°C).
للتحقق من الحصول على المركبات المطلوبة ومعقداتها تمت دراسة طيفية لتلك المركبات ومعقداتها باستخدام تقنية طيوف IR و UV-visible ومن خلال تلك الطيوف استنتجنا أن المركبات التي حضرت ومعقداتها تطابقت مع تلك التي اقترحت .
We prepared these organo phosphoric compounds: diphenyl dip-nitro phenyl ester imido diphosphate (p-nitroPhO)2P(O)N(H)P(O)(OPh)2, di nitro phenyl ester imido diphosphate (p-nitroPhO)2P(O)N(H)P(O)(OH)2. It was used to prepare their complexes with Ce(III) and Ce(IV) in alcohol . We mixed Alcoholic solution for cerium(III)nitrate and cerium(IV)sulphate both alone with alcoholic solution for organophosphoric compounds in the low temperature (-15°C).
To verify obtain the required compounds and their complexes we study it by using IR and UV-Visible technology . Then we concluded that the prepared compounds and their complexes coincided with those that have been proposed.
Downloads
Published
How to Cite
Issue
Section
License
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
The authors retain the copyright and grant the right to publish in the magazine for the first time with the transfer of the commercial right to the Tishreen University Journal -Basic Sciences Series
Under a CC BY- NC-SA 04 license that allows others to share the work with of the work's authorship and initial publication in this journal. Authors can use a copy of their articles in their scientific activity, and on their scientific websites, provided that the place of publication is indicted in Tishreen University Journal -Basic Sciences Series . The Readers have the right to send, print and subscribe to the initial version of the article, and the title of Tishreen University Journal -Basic Sciences Series Publisher
journal uses a CC BY-NC-SA license which mean
You are free to:
- Share — copy and redistribute the material in any medium or format
- Adapt — remix, transform, and build upon the material
- The licensor cannot revoke these freedoms as long as you follow the license terms.
- Attribution — You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
- NonCommercial — You may not use the material for commercial purposes.
- ShareAlike — If you remix, transform, or build upon the material, you must distribute your contributions under the same license as the original.
- No additional restrictions — You may not apply legal terms or technological measures that legally restrict others from doing anything the license permits.